Character: Nonohara Himeko
Description: The main female character. Very lively but quite tomboyish. Seems to fall in love with Daichi, although she has recently had a crush on Hasekura senpai. She is a member of the Drama Club.
Character: Pokota
Description: A lion doll which Himeko likes most. Due to the side effect of the magic ribbon, it can move and talk freely. She has helped Himeko to solve a lot of problems.
Character: Kobayashi Daichi
Description: The main male character. He was welcomed by many girls in school, including Hime-chan. Also, he always save Hime-chan when she's in danger.
Character: Nonohara Aiko
Description: The elder sister of Himeko. She is more feminine and likes Hasekura senpai.
Character: Mori Manami
Description: A friend of Himeko, likes Takada.
Character: Icchan
Description: Another friend of Himeko.
Character: Hobino Hiraku
Description: She likes Daichi very much, and declares Hime-chan as her enemy.
Character: Kobayshi Shintaro
Description: The younger brother of Daichi
Character: Nonohara Yumeko
Description: The younger sister of Himeko, who is a friend of Shintaro
Character: Nonohara Hanako
Description: The mother of Himeko, is a fiction writer.
Character: Nonohara Taro
Description: The father of Himeko, who is a director of the films.
Character: Takada
Description: A friend of Daichi, who likes Manami.
Character: Gori Gensei
Description: A serious but sometimes careless teacher of Himeko and Daichi.
Character: Hijuri Yuka
Description: A new comer of the school, who is a famous star. She likes Daichi very much.
Character: Hasekura senpai
Description: A chief member of the Drama Club, who likes Aiko.
Character: Hasekura Emi
Description: The younger sister of Hasekura senpai.
Character: Hastune
Description: An elder girl who lives near Himeko and wants to be a teacher. She only appears in episode 34.
Character: Erika
Description: The princess of the Land of Magic. She borrows the magic ribbon to Hime-chan for one year, and during these time she can watch her via her crystal ball.
Character: Sei Array
Description: A person who comes from the Land of Magic, but was sent to the Human World for one year. He likes Hime-chan.
Character: Camille
Description: The look-a-like of Daichi, who likes cheating.
Character: Ren
Description: The servant of Erika.
Character: Robelia
Description: The look-a-like of Hikaru.
Character: King
Description: The king of the Land of Magic.
Character: Queen
Description: The queen of the Land of Magic.
Character: Pink
Description: The pet of Erika, who likes Pokota.
Character: Chappy
Description: A magic brush which helps Erika to travel to the Human World.
Character: Mac and Ho
Description: Two magic creatures who come to the Human World accidentally. They were soon caught by Hime-chan and were locked in the magic palette and the magic feather.